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Bobby Moore captained the England football team during their triumphant 1966 World Cup campaign. He is renowned for his exceptional leadership on and off the pitch, as well as his defensive skills. Under his captaincy, England secured their first and only World Cup title, defeating West Germany in a dramatic final. Moore’s performance throughout the tournament was pivotal, as he was instrumental in organizing the team’s defense and leading them with composure. The victory in 1966 is still celebrated as a defining moment in England's football history, solidifying Moore’s legacy as one of the greatest captains of the sport.

The other individuals listed captained the national team at different times or played key roles but not during the 1966 World Cup. Gary Lineker is known for being a prolific goal scorer, Wayne Rooney is recognized as one of England's top players in modern football, and David Beckham was a prominent figure in the late 1990s and early 2000s but did not play in the 1966 World Cup.